Progress in Inorganic Chemistry, Volume 57

PROGRESS in Inorganic Chemistry

The cutting edge of scientific reporting

Nowhere is creative scientific talent busier than in the world of inorganic chemistry experimentation. Progress in Inorganic Chemistry continues in its tradition of being the most respected avenue for exchanging innovative research. This series provides inorganic chemists and materials scientists with a forum for critical, authoritative evaluations of advances in every area of the discipline. With contributions from internationally renowned chemists, this latest volume offers an in-depth, far-ranging examination of the changing face of the field, providing a tantalizing glimpse of the emerging state of the science.

"This series is distinguished not only by its scope and breadth, but also by the depth and quality of the reviews." —Journal of the American Chemical Society

"[This series] has won a deservedly honored place on the bookshelf of the chemist attempting to keep afloat in the torrent of original papers on inorganic chemistry."

—Chemistry in Britain

CONTENTS OF VOLUME 57

Mechanisms of Water Oxidation Catalyzed by Ruthenium Coordination Complexes (Aurora E. Clark and James K. Hurst)

Biomimetic and non-biological dinuclear Mx+-complex catalyzed alcoholysis reactions of phosphoryl transfer reactions (R. Stan Brown)

Photoactivated DNA Cleavage and Anticancer Activity of 3d-Metal Complexes (Akhil R. Chakravarty and Mithun Roy)

Design and Evolution of Artificial Metalloenzymes: Biomimetic Aspects (Marc Creus and Thomas R.Ward)

Functionalization of Fluorinated Aromatics by Nickel-Mediated C–H and C–F Bond Oxidative Addition: Prospects for the Synthesis of Fluorine-Containing Pharmaceuticals (Samuel A. Johnson, Jillian A. Hatnean, Meghan E. Doster)

DNA-Based Metal Catalysis (Jens Oelerich and Gerard Roelfes)

Metallo-lactamases and their Synthetic Mimics: Structure, Function and Catalytic Mechanism (Muthaiah Umayal, A. Tamilselvi, and Govindasamy Mugesh)

A New Class of Nanostructured Inorganic-Organic Hybrid Semiconductors Based on II-VI Binary Compounds (Jing Li and Ruibo Zhang)

Oxygen Evolution Reaction Chemistry of Oxide-Based Electrodes (Yogesh Surendranath and Daniel G. Nocera)

Chapter 1 Mechanisms of Water Oxidation Catalyzed by Ruthenium Coordination Complexes 1
AURORA E. CLARK and JAMES K. HURST

Chapter 2 Biomimetic and Nonbiological Dinuclear Mxþ Complex-Catalyzed Alcoholysis Reactions of Phosphoryl Transfer Reactions 55
R. STAN BROWN

Chapter 3 Photoactivated DNA Cleavage and Anticancer Activity of 3d Metal Complexes 119
AKHIL R. CHAKRAVARTY and MITHUN ROY

Chapter 4 Design and Evolution of Artificial Metalloenzymes: Biomimetic Aspects 203
MARC CREUS and THOMAS R. WARD

Chapter 5 Functionalization of Fluorinated Aromatics by Nickel-Mediated C–H and C–F Bond Oxidative Addition: Prospects for the Synthesis of Fluorine-Containing Pharmaceuticals 255
SAMUEL A. JOHNSON, JILLIAN A. HATNEAN, and MEGHAN E. DOSTER

Chapter 6 DNA Based Metal Catalysis 353
JENS OELERICH and GERARD ROELFES

Chapter 7 Metallo-b-lactamases and Their Synthetic Mimics: Structure, Function, and Catalytic Mechanism 395
MUTHAIAH UMAYAL, A. TAMILSELVI, and GOVINDASAMY MUGESH

Chapter 8 A New Class of Nanostructured Inorganic–Organic Hybrid Semiconductors Based on II–VI Binary Compounds 445
JING LI and RUIBO ZHANG

Chapter 9 Oxygen Evolution Reaction Chemistry of Oxide-Based Electrodes 505
YOGESH SURENDRANATH and DANIEL G. NOCERA

Subject Index 561

Cumulative Index 593

Kenneth D. Karlin, PhD, is Ira Remsen Chair in Chemistry and Professor of Chemistry at Johns Hopkins University. He received his PhD from Columbia University.